Nach ein bisschen Suchen habe ich folgende Lösung gefunden:
http://www.axelsegebrecht.com/how-to/run-multiple-instances-of-skype/
Funktioniert super
LG,
Lessy

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Most annoying differences with the new Skype 4.0 vs. 3.8
- Autostart: Even autostarts, when “Load with windows” is disabled in the options-tab.
Additionally, it is literally nowhere to be found, how Skype autostarts. Even Sysinternals AUTOSTARTS does not find the call-procedure. That’s not acceptable! I want to start the program when I want, not when it [...]

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